CGMNQ - LEAD-ACID BATTERY

Product Identification

Product ID:LEAD-ACID BATTERY
MSDS Date:02/01/1996
FSC:6140
NIIN:01-441-3512
MSDS Number: CGMNQ

Responsible Party
EXIDE CORP.-GENERAL BATTERY CORP
645 PENN STREET
READING, PA 19601
US

Emergency Phone: 215-378-0527/800-424-9300(CHEMTREC)

Info Phone: 215-378-0527

Cage: 08163

Contractor
EXIDE CORP.-GENERAL BATTERY CORP
READING, PA 19601 US

Telephone: 215-378-0527/800-424-9300(CHEMTREC)

Cage: 08163

Ingredients

LEAD (SARA III)

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 53%

OSHA PEL 0.05 MG/M3;1910.1025

ACGIH TLV: 0.15 MG/M3;DUST 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB


ANTIMONY (SARA III)

CAS: 7440-36-0

RTECS: CC4025000

Fraction By Weight: 0.2-2.0%

OSHA PEL 0.5 MG/M3

ACGIH TLV: 0.5 MG SB/M3; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS


ARSENIC (SARA III)

CAS: 7440-38-2

RTECS: CG0525000

Fraction By Weight: 0.003%

OSHA PEL 0.5 MG/M3 (AS)

ACGIH TLV: 0.01,A1 MG/M3; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB


CALCIUM, METAL

CAS: 7440-70-2

RTECS: EV8040000

Fraction By Weight: 0.02%


TIN

CAS: 7440-31-5

RTECS: XP7320000

Fraction By Weight: 0.06%

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3; 9192


ELECTROLYTE (SULFURIC ACID/WATER/SOLUTION)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 30-40%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS


POLYPROPYLENE

CAS: 9003-07-0

RTECS: TR5000000

Fraction By Weight: 5-6%


SILICA, CRYSTALLINE - FUSED

CAS: 60676-86-0

RTECS: VV7328000

Fraction By Weight: 3-5%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.1 MG/M3 RDUST;9596

Hazards

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION:VAPORS OR MIST MAY CAUSE
SEVERE RESPIRATORY IRRITATION. INHALATION OF DUST OR LEAD DUST OR
FUMES MAY CAUSE IRRATION OF UPPER RESPIRATORY TRACT AND LUNGS.
INGESTION; MAY CAUSE SEVERE IRRITAT ION OF MOUTH, THROAT, ESOPHAGUS
AND STOMACH AND MAY CAUSE ABDOMINAL PAIN, NAUSEA, VOMITING,
DIARRHEA AND CRAMPS.
Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS
CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:SEVERE SKIN IRRITATION, DAMAGE TO CORNEA, UPPER
RESPIRATORY IRRITATION, HEADACHE, FATIGUE, ABDOMINAL PAIN, LOSS OF
APPETITE, MUSCULAR ACHES AND WEAKNESS, SLEEP DISTURBANCES AND
IRRITABILITY. EROSION O F TOOTH ENAMEL, INFLAMMATION OF NOSE,
THROAT AND BRONCHIAL TUBES, ANEMIA, NEUROPHATY, PARTICULARLY OF THE
MOTOR NERVES.
Medical Cond Aggravated by Exposure:LUNG DAMAGE AND AGGRAVATED
PULMONARY CONDITIONS, SKIN DISEASE AND SOME FORMS OF KIDNEY, LIVER
AND NEUROLOGIC DISEASE MAY BE AGGRAVATED BY EXPOSURE.

First Aid

First Aid:INHALATION: REMOVE FROM EXPOSURE, GARGLE, WASH NOSE AND LIPS.
IF BREATHING IS DIFFICULT GIVE OXYGEN. CONSULT A PHYSCIAN.
INGESTION: GIVE LARGE QUANTITIES OF WATER, DO NOT INDUCE VOMITING.
CALL A PHYSC IAN. SKIN: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES, REMOVE ALL CONTAMINATED CLOTHING. EYES: FLUSH
IMMEDIATELY WITH WATER FOR 15 MINUTES. CONSULT A DOCTOR.

Fire Fighting

Flash Point:NOT APPLICABLEN/
Lower Limits:4.1 %
Upper Limits:74.2 %
Extinguishing Media:CO2, FOAM, DRY CHEMICAL, HALOGEN
Fire Fighting Procedures:IF BATTERIES ARE ON CHARGE, SHUT OFF POWER.
USE POSITIVE PRESSURE, SCBA, WATER APPLIED TO ELECTROLYTE GENERATES
HEAT AND MAY SPLATTER.
Unusual Fire/Explosion Hazard:HIGHLY FLAMMABLE HYDGROGEN GAS IS
GENERATED DURING CHARGING AND OPERATING OF BATTERIES. KEEP HEAT AND
SPARKS AWAY.

Accidental Release

Spill Release Procedures:STOP FLOW OF MATERIAL, CONTAIN/ABSORB SPILLS
WITH DRY SAND, EARTH, OR VERMIVULITE. DO NOT USE COMBUSTIBLE
MATERIALS. DO NOT DISCHARGE UNNEUTRALIZED ACID TO SEWER.
Neutralizing Agent:LIME, SODA ASH OR SODIUM BICARBONATE.

Handling

Handling and Storage Precautions:STORE IN COOL WELL VENTILATED AREA
WITH IMPERVIOUS SURFACES AND ADEQUATE CONTAINMENT IN THE EVENT OF
SPILLS, ADEQUATE WATER SUPPLY FOR SPILL CONTROL.
Other Precautions:SPENT BATTERIES: SEND TO SECONDARY LEAD SMELTER FOR
RECYCLING.

Exposure Controls

Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITIONS. WHEN
CONCENTRATION OF SULFURIC ACID MIST ARE KNOWN TO EXCEED PEL USE
NIOSH OR MSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:STORE AND HANDLE IN WELL VENTILATED AREA. IF MECHANICAL
VENTILATION IS USED, COMPONENTS MUST BE ACID-RESISTANT.
Protective Gloves:ACID RESISTANT W/ELBOW LENGTH GAUNTLET
Eye Protection:CHEMICAL GOGGLES OR FACE SHIELD
Other Protective Equipment:ACID RESISTANT APRON. ACID RESISANT CLOTHING
IF CONDITION WARRANT.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
IN AREAS WHERE SULFURIC ACID IS HANDLED IN CONCENTRATIONS GREATER THAN
1% EMERGENCY EYE WASHES AND SHOWERS SHOULD BE PROVIDED WITH
UNLIMITED WATER SUPPLY.

Chemical Properties

HCC:N1
Boiling Pt:B.P. Text:203-240F
Vapor Pres:10 MMHG
Vapor Density:>1
Spec Gravity:1.230-1.350
Evaporation Rate & Reference:<1
Solubility in Water:100%
Appearance and Odor:A BATTERY IS A MANUFACTURED ARTICE, NO APPARENT
ODOR.

Stability

Stability Indicator/Materials to Avoid:YES
COMBUSTIBLES AND ORGANIC MATERIALS MAY CAUSE FIRE AND EXPLOSION. ALSO
REACTS WITH STRONG REDUCING AGENTS.
Stability Condition to Avoid:PROLONGED OVERCHARGE, SOURCES OF IGNITION.
Hazardous Decomposition Products:SULFURIC ACID:SULFUR TRIOXIDE, CARBON
MONOXIDE, SULFURIC ACID MIST, SULFUR DIOXIDE, HYDROGEN.

Disposal

Waste Disposal Methods:PLACE NEUTRALIZED SLURRY INTO SEALED CONTAINERS
AND DISPOSE OF AS HAZARDOUS WASTE AS APPLICABLE. LARGE
WATER-DILUTED SPILLS, AFTER NEUTRALIZATIOM AND TESTING SHOULD BE
MANAGED IN ACCORDANCE WITH APPRO VED LOCAL STATE AND FEDERAL
REQUIREMENTS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.